NUCLEOPHILIC PROPERTIES OF BUTYLLITHIUM VERSUS FREE CARBOXYLIC-ACIDS

被引：10

作者：

EINHORN, C ^{[1
]}

EINHORN, J ^{[1
]}

LUCHE, JL ^{[1
]}

机构：

[1] UNIV GRENOBLE 1,ETUD DYNAM & STRUCT SELECT LAB,BATIMENT CHIM,BP 53X,F-38041 GRENOBLE,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 24期

关键词：

CARBOXYLIC ACIDS; BUTYLLITHIUM; NUCLEOPHILIC VERSUS BASIC ATTACK; COMPETITIVE PATHWAYS;

D O I：

10.1016/0040-4039(91)85082-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In opposition to the generally accepted idea, butyl lithium is not only a deprotonating agent for free carboxylic acids, but can also act as a nucleophile on the carbon oxygen double bond.

引用

页码：2771 / 2774

页数：4

共 8 条

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