DRAMATIC INFLUENCE OF NITROGEN-HETEROCYCLES ON THE ACTIVITY OF LOW-VALENT TITANIUM REAGENT - AN IMPROVED ONE-POT SYNTHESIS OF PHENANTHRENES

被引：6
作者：
KADAM, SM [1 ]
NAYAK, SK [1 ]
BANERJI, A [1 ]
机构：
[1] BHABHA ATOM RES CTR,DIV BIOORGAN,BOMBAY 400085,INDIA
来源：
SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 02期
关键词：
D O I：
10.1080/00397919508010799
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel low-valent titanium (LVT) induced one-pot synthesis of phenanthrenes (25-38% yield) from ortho-alkoxy aromatic aldehydes/ketones was reported by us earlier. Activity of LVT complex could be modulated rationally by using catalytic amount of pyridine. Use of this LVT-pyridine reagent system improved the yields of phenanthrenes (3) by two folds.
引用
收藏
页码：135 / 142
页数：8
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