Crystal structure of catena-poly[[(3-tert-butylpyridine-kappa N)(4-tert-butylpyridine-kappa N)cadmium]-di-mu-thiocyanato-kappa N-2:S;kappa S-2:N]

被引:0
作者
Werner, Julia [1 ]
Reinert, Thorben [2 ]
Jess, Inke [1 ]
Nather, Christian [1 ]
机构
[1] Christian Albrechts Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
[2] Christian Albrechts Univ Kiel, Inst Phys Chem, D-24118 Kiel, Germany
关键词
crystal structure; cadmium coordination polymer; mu-1,3-thiocyanate anions;
D O I
10.1107/S1600536814024647
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, [Cd( NCS)(2)(C9H13N)(2)](n), the Cd-II cations are coordinated in a slightly distorted octahedral geometry by one 3-tert-butylpyridine ligand, one 4-tert-butylpyridine ligand and two pairs of translationally-equivalent mu-1,3-bridging thiocyanate ligands, all of which are in general positions. These mu-1,3-bridging thiocyante anions bridge the Cd-II cations, forming chains that propagate parallel to the b axis.
引用
收藏
页码:M403 / +
页数:9
相关论文
共 8 条
[1]   Synthesis, structure and bonding of cadmium(II) thiocyanate systems featuring nitrogen based ligands of different denticity [J].
Banerjee, S ;
Wu, B ;
Lassahn, PG ;
Janiak, C ;
Ghosh, A .
INORGANICA CHIMICA ACTA, 2005, 358 (03) :535-544
[2]  
Brandenburg K., 2011, DIAMOND
[3]   Bis(3-tert-butylpyridine-kappa N)bis(4-tert-butylpyridine-kappa N)bis(thiocyanato-kappa N)cadmium [J].
Reinert, Thorben ;
Jess, Inke ;
Naether, Christian .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 :M1372-+
[4]   Trans-bis(3-tert-butylpyridine-kappa N) bis(4-tert-butylpyridine-kappa N) bis(thiocyanato-kappa N) manganese(II) [J].
Reinert, Thorben ;
Jess, Inke ;
Naether, Christian .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 :M1333-+
[5]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[6]  
Stoe & Cie, 2008, X AREA X RED32 X SHA
[7]   Synthesis and crystal structure determination of 0D-, 1D-and 3D-metal compounds of 4-(pyrid-4-yl)-1,2,4-triazole with zinc(II) and cadmium(II) [J].
Tahli, Anas ;
Maclaren, Jana K. ;
Boldog, Ishtvan ;
Janiak, Christoph .
INORGANICA CHIMICA ACTA, 2011, 374 (01) :506-513
[8]   publCIF: software for editing, validating and formatting crystallographic information files [J].
Westrip, Simon P. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925