BIOSYNTHESIS OF CHIMONANTHINE FROM [2-3H]TRYPTOPHAN AND [2-3H]-TRYPTAMINE

被引：22
作者：
KIRBY, GW
SHAH, SW
HERBERT, EJ
机构：
[1] Chemistry Department, University of Technology, Loughborough
来源：
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 14期
关键词：
D O I：
10.1039/j39690001916
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Conversion of (±)-[β-14C, 2-3H]tryptophan and [β-14C, 2-3H]tryptamine into (-)-chimonanthine has been shown to occur in Chimonanthus fragrans (praecox) without loss of tritium. Degradation of the alkaloid has established the predicted labelling pattern. A synthesis of [2-3H]- and [2-3H]-indole from indoxyl is recorded and the structure of diacetoxymercuri-indole is revised.
引用
收藏
页码：1916 / &
相关论文
共 20 条
12