NEW INTERMEDIATE STEPS IN THE SYNTHESIS OF LARGER NICKEL CLUSTERS

被引：44
作者：
FENSKE, D
KRAUTSCHEID, H
MULLER, M
机构：
[1] Institut Für Anorganische Chemie Der, Universität Engesserstrasse, Karlsruhe, D-W-7500
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期
关键词：
D O I：
10.1002/anie.199203211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phosphane complexes of NiCl2 react with Se(SiMe3)2 affording mixtures of cluster complexes whose structures are dependent on the phosphane ligands. Through the variation of the ligands, complexes 1-6 were isolated and structurally characterized (Phe = C2H4Ph). Cluster 2 incorporates a spirocyclic Ni5 framework, 6 a central Ni13 cuboctahedron.
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页码：321 / 323
页数：3
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