ASYMMETRIC REDUCTIONS OF ALPHA,BETA-ACETYLENIC KETONES AND ACETOPHENONE USING LITHIUM ALUMINUM-HYDRIDE COMPLEXED WITH OPTICALLY-ACTIVE 1,3-AMINO ALCOHOLS

被引：99
作者：
COHEN, N
LOPRESTI, RJ
NEUKOM, C
SAUCY, G
机构：
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1980年 / 45卷 / 04期
关键词：
D O I：
10.1021/jo01292a006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
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页码：582 / 588
页数：7
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共 33 条
[1]   ASYMMETRIC REDUCTION OF PROCHIRAL KETONES WITH CHIRAL HYDRIDE REAGENTS PREPARED FROM LITHIUM ALUMINUM-HYDRIDE AND (S)-2-(N-SUBSTITUTED AMINOMETHYL)PYRROLIDINES [J].
ASAMI, M ;
OHNO, H ;
KOBAYASHI, S ;
MUKAIYAMA, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (06) :1869-1873
[2]  
ASAMI M, 1979, HETEROCYCLES, V12, P499
[3]  
BENNETT GB, 1977, SYNTHESIS-STUTTGART, P589
[4]   RESEARCHES ON ACETYLENIC COMPOUNDS .1. THE PREPARATION OF ACETYLENIC KETONES BY OXIDATION OF ACETYLENIC CARBINOLS AND GLYCOLS [J].
BOWDEN, K ;
HEILBRON, IM ;
JONES, ERH ;
WEEDON, BCL .
JOURNAL OF THE CHEMICAL SOCIETY, 1946, (JAN) :39-45
[5]   ASYMMETRIC REDUCTION - REDUCTION OF ACETYLENIC KETONES WITH CHIRAL HYDRIDE AGENT [J].
BRINKMEYER, RS ;
KAPOOR, VM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (25) :8339-8341
[6]   SYNTHESIS OF (2R,4'R,8'R)-ALPHA-TOCOPHERYL ACETATE (VITAMIN-E ACETATE) USING [3,3] SIGMATROPIC REARRANGEMENT [J].
CHAN, KK ;
SPECIAN, AC ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (18) :3435-3440
[7]   SYNTHETIC STUDIES ON (2R,4'R,8'R)-ALPHA-TOCOPHEROL FACILE SYNTHESES OF OPTICALLY-ACTIVE, SATURATED, ACYCLIC ISOPRENOIDS VIA STEREOSPECIFIC [3,3] SIGMATROPIC REARRANGEMENTS [J].
CHAN, KK ;
COHEN, N ;
DENOBLE, JP ;
SPECIAN, AC ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (22) :3497-3505
[8]   TRANSFER OF CHIRALITY IN [2,3]SIGMATROPIC REARRANGEMENT OF ALLYLIC ALCOHOLS TO BETA,GAMMA-UNSATURATED AMIDES - PREPARATION OF OPTICALLY-ACTIVE 9-CARBON AND 14-CARBON SATURATED ISOPRENOID SYNTHONS [J].
CHAN, KK ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (24) :3828-3832
[9]   SYNTHETIC STUDIES ON 2R,4'R,8'R-ALPHA-TOCOPHEROL - ALTERNATIVE SYNTHESIS OF (2R,6R)-(+)-2,6,10-TRIMETHYLUNDECAN-1-OL, A KEY SIDE-CHAIN SYNTHON [J].
COHEN, N ;
EICHEL, WF ;
LOPRESTI, RJ ;
NEUKOM, C ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (22) :3512-3515
[10]   STUDIES ON SYNTHESIS OF (2R,4'R,8'R)-ALPHA-TOCOPHEROL ALTERNATIVE SYNTHESES OF 2-CHROMAN-ACETIC ACID INTERMEDIATES [J].
COHEN, N ;
SCOTT, JW ;
BIZZARO, FT ;
LOPRESTI, RJ ;
EICHEL, WF ;
SAUCY, G ;
MAYER, H .
HELVETICA CHIMICA ACTA, 1978, 61 (02) :837-843
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