SYNTHESIS OF EARTHY-MOLDY SMELLING COMPOUNDS .2. ETHYL ALPHA-FENCHOLS AND BETA-FENCHOLS

被引：9

作者：

GOSSELIN, P ^{[1
]}

JOULAIN, D ^{[1
]}

LAURIN, P ^{[1
]}

ROUESSAC, F ^{[1
]}

机构：

[1] ROBERTET SA, F-06333 GRASSE, FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)94718-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several stereoselective routes to both ethyl α- and β- fenchols 1α and 1β are discussed. Direct addition of ethyllithium to fenchone was the best route to 1α whereas obtention of 1β was achieved through the highly stereoselective retroethynylation of a mixture of ethynyl α- and β-fenchols 4α and 4β. © 1990.

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页码：3151 / 3154

页数：4

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