Poly[di-mu(3)-hydroxy[mu(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-kappa N-5, O-2:O-2':O-4:O-4']dicadmium]

被引:1
作者
Meng, Fan-Jin [1 ]
Jia, Heng-Qing [1 ]
Hu, Ning-Hai [1 ]
Zhou, Hua [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 11.9; mean ̄(C-C) = 0.008 Å; R factor = 0.037; single-crystal X-ray study; T = 293 K; wR factor = 0.087;
D O I
10.1107/S1600536812042444
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title polymeric complex, [Cd-2(C13H7NO4)(OH)(2)] n, consists of two independent Cd II atoms, one 5-(4-carboxyphenyl) pyridine-2-carboxylate ligand and two hydroxy groups. One Cd-II atom is six-coordinated by two O atoms from two ligand molecules and by four mu(3)-OH groups in a distorted trigonal-prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two mu(3)-OH groups, forming a distorted squarepyramidal geometry. The two independent Cd-II atoms are connected by the ligand molecules and the OH groups into a three-dimensional framework. O-H center dot center dot center dot O hydrogen bonds between the OH groups and the carboxylate O atoms are observed.
引用
收藏
页码:M1364 / +
页数:9
相关论文
共 9 条
[1]  
Ben B. C., 1951, US Patent, Patent No. 2578672
[2]  
Bruker, 2001, SADABS
[3]  
Bruker, 2007, SMART SAINT
[4]   Construction of coordination networks with high connectivity: a new 8-connected self-penetrating network based on tetranuclear metal clusters [J].
Li, Zhi-Gang ;
Wang, Guan-Hua ;
Jia, Heng-Qing ;
Hu, Ning-Hai ;
Xu, Jing-Wei ;
Batten, Stuart R. .
CRYSTENGCOMM, 2008, 10 (08) :983-985
[5]   Phosphine-free palladium acetate catalyzed Suzuki reaction in water [J].
Liu, LF ;
Zhang, YH ;
Wang, YG .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (15) :6122-6125
[6]   Pyridine- and imidazoledicarboxylates of zinc: Hydrothermal synthesis, structure, and properties [J].
Mahata, P ;
Natarajan, S .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (11) :2156-2163
[7]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[8]  
Sun Y.-Q., 2001, ANGEW CHEM INT EDIT, V44, P5814
[9]   Metal-organic frameworks based on the pyridine-2,3-dicarboxylate and a flexible bispyridyl ligand: syntheses, structures, and photoluminescence [J].
Wang, Guan-Hua ;
Li, Zhi-Gang ;
Jia, Heng-Qing ;
Hu, Ning-Hai ;
Xu, Jing-Wei .
CRYSTENGCOMM, 2009, 11 (02) :292-297