TETRAFERRIOAZAALLENIUM - PRODUCT OF A NOVEL REACTION OF COORDINATED CN-

被引：14

作者：

FEHLHAMMER, WP ^{[1
]}

SCHRODER, A ^{[1
]}

FUCHS, J ^{[1
]}

WURTHWEIN, EU ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,W-4400 MUNSTER,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1002/anie.199205901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The N-acylation of the cyano ligand in the binuclear complex anion of Na[Fe2(CN)-Cp2(CO)3] with dicarboxylic acid chlorides causes the cleavage of the C-N triple bond and the attachment of a second complex anion to form the surprisingly stable, permetalated, axially chiral 2-azaallenium ion 1, which can be isolated as a chloride. This conversion of CN- has parallels in CO chemistry both in multinuclear clusters and on surfaces. [Fe] = FeCpCO.

引用

页码：590 / 592

页数：3

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