TETRAFERRIOAZAALLENIUM - PRODUCT OF A NOVEL REACTION OF COORDINATED CN-

被引：14
|
作者：
FEHLHAMMER, WP [1 ]
SCHRODER, A [1 ]
FUCHS, J [1 ]
WURTHWEIN, EU [1 ]
机构：
[1] UNIV MUNSTER,INST ORGAN CHEM,W-4400 MUNSTER,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期
关键词：
D O I：
10.1002/anie.199205901
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The N-acylation of the cyano ligand in the binuclear complex anion of Na[Fe2(CN)-Cp2(CO)3] with dicarboxylic acid chlorides causes the cleavage of the C-N triple bond and the attachment of a second complex anion to form the surprisingly stable, permetalated, axially chiral 2-azaallenium ion 1, which can be isolated as a chloride. This conversion of CN- has parallels in CO chemistry both in multinuclear clusters and on surfaces. [Fe] = FeCpCO.
引用
收藏
页码：590 / 592
页数：3
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