INTERSYSTEM CROSSING YIELDS IN RUTHENIUM(II) AND OSMIUM(II) PHOTOSENSITIZERS

被引：180

作者：

DEMAS, JN

TAYLOR, DG

机构：

[1] Department of Chemistry, University of Virginia, Charlottesville

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1021/ic50201a044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Originally the efficiencies, φ‘‘s, of populating the sensitizing charge-transfer excited states of Ru(II) and Os(II) photosensitizers were claimed to be unity. Recent experimental results have raised questions concerning this claim. This paper reexamines the question of the φ‘‘s, of these photosensitizers. With both photochemical and spectroscopic data, the early claim of unity φ‘‘s, is supported. © 1979, American Chemical Society. All rights reserved.

引用

页码：3177 / 3179

页数：3

共 31 条

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