Crystal structure of 2-[(dichloromethane)sulfonyl]pyridine

被引：1
|
作者：
Chen, Zhiqiu [1 ]
Bolat, Hembat [1 ]
Wan, Xing [1 ]
Li, Ya [1 ]
机构：
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, 333 Longteng Rd, Shanghai, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
crystal structure; sulfone; pyridine derivative; hydrogen bonding; pi-pi stacking;
D O I：
10.1107/S1600536814025148
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, C6H5Cl2NO2S, contains two molecules with similar conformations (r.m.s. overlay fit for the non-H atoms = 0.067 angstrom). Atoms attached to the pendent Csp(3)-S bond are arranged in a staggered conformation with one of the Cl atoms anti to the C atom in the aromatic ring [C-S-C-Cl torsion angles = 178.41 (11) and -176.70(13)degrees]. In the crystal, molecules are linked by CH center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network, and weak aromatic pi-pi stacking is also observed [centroid-centroid separation = 3.8902 (17) angstrom].
引用
收藏
页码：O1272 / +
页数：6
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