THE USE OF FURANYL TITANIUM COMPOUNDS FOR THE SYNTHESIS OF 2,4-SUBSTITUTED FURANS

被引：16

作者：

HAARMANN, H ^{[1
]}

EBERBACH, W ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ORGAN CHEM & BIOCHEM,ALBERTSTR 21,W-7800 FREIBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)92116-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The metal derivatives 2-5, derived from the protected 4-bromo-2-furancarbaldehydes 1a,b, were reacted with the bifunctional reagent 6 bearing an aldehyde and an ester function. Whereas the Li-, Mg- and Zn- species turned out to be either unselective and/or too unreactive, the Ti-derivatives 5a,b gave the addition products 7a,b in good yield and with high chemoselectivity.

引用

页码：903 / 906

页数：4

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