SINGLE-CRYSTAL EPR SPECTROSCOPY ON [FE-57(NO)(S(2)CNET(2))(2)] - THE TRIPLET SIGNAL IN THE EPR-SPECTRUM OF [FE(S(2)CNET(2))(3)]

被引：6

作者：

KIRMSE, R

SALUSCHKE, S

MOLLER, E

REIJERSE, EJ

GELERINTER, E

DUFFY, NV

机构：

[1] KENT STATE UNIV, DEPT PHYS, KENT, OH USA

[2] KENT STATE UNIV, DEPT CHEM, KENT, OH USA

[3] UNIV NIJMEGEN, MOLEK SPEKT ABT, NIJMEGEN, NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199414971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Traces of nitrate in the starting material FeCl3 lead to the formation of the analogous nitrosyliron(I) complex 2 during the synthesis of the tris(dithiocarbamato)iron complex 1. EPR studies on 57Fe‐labeled 2 show that this complex gives rise to the triplet signal in the EPR spin‐crossover studies on 1 at g = 2.0 that has been discussed for a long time. (Figure Presented.) (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1497 / 1499

页数：3

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