RADICAL CYCLIZATION REACTIONS - CYCLOPROPANE RING FORMATION BY 3-EXO-CYCLIZATION OF 5-PHENYLTHIO-3-PENTENYL RADICALS

被引：21

作者：

CEKOVIC, Z ^{[1
]}

SAICIC, R ^{[1
]}

机构：

[1] INST CHEM TECHNOL & MET,BELGRADE,YUGOSLAVIA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)98035-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Free radical cyclopropane ring closure was accomplished by thermal decomposition of thiohydroxamic esters of 6-phenylthio-4-hexencic acids. When the reaction was performed in the presence of acrylonitrile; an addition/cyclization/elimination process took place and the corresponding cyclopentanecarbonitriles were obtained. © 1990.

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页码：6085 / 6088

页数：4

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