EVIDENCE OF REACTIVE INTERMEDIATES IN SECO/CYCLO ISOMERIZATIONS BY LOW-TEMPERATURE TECHNIQUES

被引：16
作者：
QUINKERT, G
机构：
[1] Institut für Organische Chemie der Technischen Hochschule, Braunschweig
来源：
PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1968年 / 7卷 / 06期
关键词：
D O I：
10.1111/j.1751-1097.1968.tb08064.x
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Abstract— Matrix isolation methods at low temperatures have been used to trap seco‐isomeric intermediates in photochemical electrocyclic transformations of cyclo isomers. The stereochemical behavior is found to be consistent with the Woodward‐Hoffman rules. Se han usado soluciones a bajas temperaturas para atrapar intermediaries seco‐isoméricos en transformacíones fotoquímicas electrocíclicas de cicloisómeros. Se ha encontrado que el comportamiento estereoquímico es consistente con las reglas de Woodward y Hoffmann. Copyright © 1968, Wiley Blackwell. All rights reserved
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页码：783 / &
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