NMR-STUDIES OF THE COMPLEXES TRANS-[M(ETA-2-H2)(H)(PH2PCH2CH2PET2)2]X (M=FE,X=BPH4 - M=OS,X=BF4) - EVIDENCE FOR UNEXPECTED SHORTENING OF THE H-H BOND

被引：34

作者：

BAUTISTA, MT

EARL, KA

MORRIS, RH

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA

[2] UNIV TORONTO,SCARBOROUGH CAMPUS,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

INORGANIC CHEMISTRY | 1988年 / 27卷 / 07期

关键词：

D O I：

10.1021/ic00280a600

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1124 / 1126

页数：3

共 11 条

[1] NMR PROPERTIES OF THE COMPLEXES TRANS-[M(ETA-2-H2)(H)(PET2CH2CH2PET2)2]+, M = FE, RU, OS - INTRAMOLECULAR EXCHANGE OF ATOMS BETWEEN ETA-2-DIHYDROGEN AND HYDRIDE LIGANDS
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[5] SYNTHESIS AND PROPERTIES OF A SERIES OF RUTHENIUM DIHYDROGEN COMPLEXES
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[6] MOLECULAR-HYDROGEN COMPLEXES - THE EFFECT OF STERIC FACTORS ON THE PROTONATION OF THE MONOHYDRIDES [(ETA-5-C5H5)RU(PH2P(CH2)NPPH2)H] (N=1-3)
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1675 - 1676
[7] SOME MOLECULAR-HYDROGEN COMPLEXES OF IRIDIUM
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[8] EARL KE, 1987, THESIS U TORONTO
[9] MOLECULAR-HYDROGEN COMPLEXES OF THE TRANSITION-METALS .4. PREPARATION AND CHARACTERIZATION OF MO(CO)3(PR3)2(ETA-2-H-2), W(CO)3(PR3)2(ETA-2-H-2) AND EVIDENCE FOR EQUILIBRIUM DISSOCIATION OF THE H-H BOND TO GIVE MH2(CO)3(PR3)2
KUBAS, GJ
UNKEFER, CJ
SWANSON, BI
FUKUSHIMA, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (22) : 7000 - 7009
[10] MOLECULAR-HYDROGEN COMPLEXES .5. ELECTRONIC CONTROL OF ETA2-H2 VERSUS DIHYDRIDE COORDINATION - DIHYDRIDE STRUCTURE OF MOH2(CO)(R2PC2H4PR2)2 FOR R = ET, I-BU VERSUS ETA2-H2 FOR R = PH
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) : 8113 - 8115

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