REACTIONS OF A BULKY ARYLGALLIUM DICHLORIDE WITH ORGANOMETALLIC MONOANIONS - FORMATION OF A DIGALLOXANE WITH ORGANOMETALLIC SUBSTITUENTS

被引：30

作者：

COWLEY, AH ^{[1
]}

DECKEN, A ^{[1
]}

OLAZABAL, CA ^{[1
]}

NORMAN, NC ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 16期

关键词：

D O I：

10.1021/ic00094a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the bulky arylgallium dichloride Ar'GaCl2 OV = 2,4,6-t-Bu3C6H2) with 2.2 equiv of Na[Co(CO)4] in Et2O solution affords the intermetallic derivative [Ga(Ar'){Co(CO4)2] (1). Interestingly, the corresponding reaction of Ar'GaCl2 With Na[Mn(CO)5] in Et2O solution affords a mixed crystal of the first digalloxane, [Ga(Ar'){Mn-(CO)5}]2O (2) and [Ga(Ar)(Cl){Mn(CO)5}] (3). The structures of 1-3 have been established by X-ray crystallography.

引用

页码：3435 / 3437

页数：3

共 15 条

[1] GALLIUM AND INDIUM COMPOUNDS CONTAINING 3 DIFFERENT SUBSTITUENTS - CRYSTAL AND MOLECULAR-STRUCTURE OF [(ME3CCH2)CLGAPPH2]3 [J].

BEACHLEY, OT ;

MALONEY, JD ;

ROGERS, RD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 449 (1-2) :69-75

[2] SYNTHETIC AND STRUCTURAL STUDIES ON ORGANOTRANSITION METAL-GALLIUM COMPLEXES [J].

CAMPBELL, RM ;

CLARKSON, LM ;

CLEGG, W ;

HOCKLESS, DCR ;

PICKETT, NL ;

NORMAN, NC .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (01) :55-59

[3] CHEMICAL VAPOR-DEPOSITION OF COGA AND PTGA2 THIN-FILMS FROM MIXED-METALORGANOMETALLIC COMPOUNDS [J].

CHEN, YJ ;

KAESZ, HD ;

KIM, YK ;

MULLER, HJ ;

WILLIAMS, RS ;

XUE, ZL .

APPLIED PHYSICS LETTERS, 1989, 55 (26) :2760-2762

[4] CHEMICAL BEAM EPITAXY OF GAAS FILMS USING SINGLE-SOURCE PRECURSORS [J].

EKERDT, JG ;

SUN, YM ;

JACKSON, MS ;

LAKHOTIA, V ;

PACHECO, KA ;

KOSCHMIEDER, SU ;

COWLEY, AH ;

JONES, RA .

JOURNAL OF CRYSTAL GROWTH, 1992, 124 (1-4) :158-164

[5] BETA-COGA AND EPSILON-NIIN FILMS FROM ORGANOMETALLIC SINGLE-SOURCE PRECURSORS - LIGAND-CONTROL OF THE FILM COMPOSITION [J].

FISCHER, R ;

SCHERER, W ;

KLEINE, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05) :748-750

[6] ORGANO-EARTH METAL-COMPLEXES OF D-BLOCK ELEMENTS .4. SINGLE-POT SYNTHESIS OF VOLATILE ORGANOGALLIOCOBALT COMPLEXES, MOLECULAR-STRUCTURE OF (MU-[3-(DIETHYLAMINO)PROPYL]GALLIO)[BIS(TETRACARBONYLCOBALT)] [J].

FISCHER, RA ;

BEHM, J ;

PRIERMEIER, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 429 (03) :275-286

[7]

FISHER RA, 1993, ANGEW CHEM INT EDIT, V32, P746

[8] STUDY OF COGA DEPOSITION FROM THE SINGLE-SOURCE PRECURSOR (CO)4COGACL2 (THF) [J].

MAURY, F ;

BRANDT, L ;

KAESZ, HD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 449 (1-2) :159-165

[9] SYNTHESIS AND CHARACTERIZATION OF BULKY ARYL DERIVATIVES OF THE HEAVIER MAIN GROUP-3 ELEMENTS [J].

PETRIE, MA ;

POWER, PP ;

DIAS, HVR ;

RUHLANDTSENGE, K ;

WAGGONER, KM ;

WEHMSCHULTE, RJ .

ORGANOMETALLICS, 1993, 12 (04) :1086-1093

[10]

PREUT M, 1974, CHEM BER, V107, P2863

← 1 2 →