THE 1ST HIGHLY ASYMMETRIC PUMMERER-TYPE REACTION IN CHIRAL ACYCLIC SULFOXIDES - CHEMISTRY OF O-SILYLATED KETENE ACETALS

被引：28
|
作者：
KITA, Y
SHIBATA, N
YOSHIDA, N
机构：
[1] Faculty of Pharmaceutical Sciences, Osaka University 1-6, Suita, Osaka, 565, Yamada-oka
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 25期
关键词：
PUMMERER REACTION; O-SILYLATED KETENE ACETALS; CHIRAL SULFOXIDES; ACYCLIC; ASYMMETRIC;
D O I：
10.1016/S0040-4039(00)60616-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chiral sulfoxides (4) were reacted with O-silylated ketene acetal (2) in acetonitrile to give the corresponding alpha-siloxysulfides (5) in high degree of stereochemistry and high yields.
引用
收藏
页码：4063 / 4066
页数：4
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