A CONVENIENT SYNTHESIS OF EPOXIDES FROM OLEFINS USING MOLECULAR-OXYGEN IN THE ABSENCE OF METAL-CATALYSTS

被引：100

作者：

KANEDA, K ^{[1
]}

HARUNA, S ^{[1
]}

IMANAKA, T ^{[1
]}

HAMAMOTO, M ^{[1
]}

NISHIYAMA, Y ^{[1
]}

ISHII, Y ^{[1
]}

机构：

[1] KANSAI UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 564,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 45期

关键词：

EPOXIDATION; OLEFIN; MOLECULAR OXYGEN; ALDEHYDE;

D O I：

10.1016/S0040-4039(00)61786-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The system consisting of molecular oxygen and aldehydes (e.g., isobutyraldehyde and pivalaldehyde) oxidizes various olefins to give epoxides in high yield's at 40-degrees-C for 3 - 6 h.

引用

页码：6827 / 6830

页数：4

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