A CONVENIENT SYNTHESIS OF EPOXIDES FROM OLEFINS USING MOLECULAR-OXYGEN IN THE ABSENCE OF METAL-CATALYSTS

被引:100
作者
KANEDA, K [1 ]
HARUNA, S [1 ]
IMANAKA, T [1 ]
HAMAMOTO, M [1 ]
NISHIYAMA, Y [1 ]
ISHII, Y [1 ]
机构
[1] KANSAI UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 564,JAPAN
关键词
EPOXIDATION; OLEFIN; MOLECULAR OXYGEN; ALDEHYDE;
D O I
10.1016/S0040-4039(00)61786-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The system consisting of molecular oxygen and aldehydes (e.g., isobutyraldehyde and pivalaldehyde) oxidizes various olefins to give epoxides in high yield's at 40-degrees-C for 3 - 6 h.
引用
收藏
页码:6827 / 6830
页数:4
相关论文
共 9 条
  • [1] THIANTHRENE 5-OXIDE AS A MECHANISTIC PROBE FOR ASSESSING THE ELECTRONIC CHARACTER OF OXYGEN-TRANSFER AGENTS
    ADAM, W
    HAAS, W
    LOHRAY, BB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) : 6202 - 6208
  • [2] Filippova TY, 1982, RUSS CHEM REV, V51, P582, DOI DOI 10.1070/RC1982V051N06ABEH002867
  • [3] GRUBBS GT, 1985, J AM CHEM SOC, V107, P5790
  • [4] HUDLICKY M, 1990, ACS MONOGRAPHY AM CH, V186
  • [5] DIRECT EPOXY ALCOHOL SYNTHESIS FROM CYCLIC OLEFINS USING O2 AND VO(ACAC)2-AIBN CATALYST SYSTEM
    KANEDA, K
    JITSUKAWA, K
    ITOH, T
    TERANISHI, S
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (15) : 3004 - 3009
  • [6] RUTHENIUM-CATALYZED OXIDATIVE CLEAVAGE REACTION OF CARBON-CARBON DOUBLE-BONDS USING MOLECULAR-OXYGEN
    KANEDA, K
    HARUNA, S
    IMANAKA, T
    KAWAMOTO, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (21) : 1467 - 1468
  • [7] Sheldon R.A., 1981, METAL CATALYZED OXID
  • [8] TAKENOUCHI T, 1972, OIL CHEM, P189
  • [9] DIRECT EPOXIDATION OF OLEFINS CATALYZED BY NICKEL(II) COMPLEXES WITH MOLECULAR-OXYGEN AND ALDEHYDES
    YAMADA, T
    TAKAI, T
    RHODE, O
    MUKAIYAMA, T
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (07) : 2109 - 2117