ORGANOTIN CHEMISTRY .16. REACTIONS OF STANNANE WITH ORGANIC FUNCTIONAL-GROUPS

被引：6

作者：

REIFENBERG, GH ^{[1
]}

CONSIDINE, WJ ^{[1
]}

机构：

[1] ELF ATOCHEM N AMER INC,KING OF PRUSSIA,PA 19406

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 08期

关键词：

D O I：

10.1021/om00032a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of stannane with a variety of organic substrates have been studied. Benzaldehyde, acetone, nitrobenzene, and 2-nitropropane are reduced to benzyl alcohol, isopropyl alcohol, aniline, and isopropylamine, respectively. With boron trifluoride etherate and benzyl chloride, stannane undergoes halogen-hydrogen exchange, while with isopropylamine and acetic acid, it is decomposed catalytically into its elements. Tetrakis(2-cyanoethyl)tin is formed by the addition of stannane to acrylonitrile. Stannane did not react with the following: (a) ethyl acetate, (b) methyl acrylate, (c) aniline, (d) triethylamine, (e) dimethylacetamide, and (f) N-ethylacetamide. The results obtained with stannane are for the most part analogous to those reported for the corresponding organotin hydrides.

引用

页码：3015 / 3018

页数：4

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