Stereochemistry of the electroreduction of the C-Cl bond

被引：14

作者：

Czochralska, Barbara ^{[1
]}

机构：

[1] Univ Warsaw, Dept Biophys, Inst Inorgan Chem, Warsaw, Poland

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 05期

关键词：

D O I：

10.1016/0009-2614(67)85062-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electroreduction mechanism of alpha-halogen derivatives of organic compounds in proton donating solvents was investigated on the exampie of optically active 2-phenyl-2-chloropropionic acid. It was shown that the electroreduction occurs with inversion of configuration according to the SN2 mechanism.

引用

页码：239 / 241

页数：3

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