MECHANISM OF SOLVOLYSIS OF 2-HALOGENOALKYLSILANES .I. STERIC ASPECTS

被引：78

作者：

JARVIE, AWP

HOLT, A

THOMPSON, J

机构：

[1] Chemistry Department, University of Aston in Birmingham

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 07期

关键词：

D O I：

10.1039/j29690000852

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The solvolysis of erythro-1,2-dibromopropyltrimethylsilane in aqueous ethanol at room temperature has been shown to result in the highly stereospecific trans-elimination of trimethylbromosilane. A mechanism is suggested which involves initial cleavage of the carbon-halogen bond assisted by participation of the silicon with the developing positive charge on the carbon atom.

引用

页码：852 / &

共 19 条

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