RESONANCE RAMAN-SPECTRA OF THE O-2 ADDUCTS OF COBALT PICKET-FENCE PORPHYRIN COMPLEXES OF 3,5-DICHLOROPYRIDINE

被引：4
|
作者：
PRONIEWICZ, LM
GOLUS, J
NAKAMOTO, K
KINCAID, JR
机构：
[1] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53233
[2] JAGIELLONIAN UNIV,DEPT CHEM,KRAKOW,POLAND
来源：
JOURNAL OF RAMAN SPECTROSCOPY | 1995年 / 26卷 / 01期
关键词：
D O I：
10.1002/jrs.1250260106
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Resonance Raman spectra are reported for the O-16(2) and O-18(2) adducts of cobalt porphyrin complexes with 3,5-dichloropyridine (DCP) for three different 'picket-fence' porphyrins. It is shown that the nu(O-O) effectively couples with an internal mode of DCP giving rise to complicated spectral patterns. These spectral patterns were carefully analyzed to reveal the inherent wavenumbers of nu(O-O) which are shown to vary as expected, given the known relative hydrogen bonding capabilities of the three different superstructured porphyrins.
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页码：27 / 30
页数：4
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