CRYSTAL SMECTIC-B PHASE FROM A MESOMORPHIC FERROCENE DERIVATIVE

被引：15

作者：

DESCHENAUX, R ^{[1
]}

MARENDAZ, JL ^{[1
]}

SANTIAGO, J ^{[1
]}

机构：

[1] UNIV HULL,SCH CHEM,KINGSTON HULL HU6 7RX,N HUMBERSIDE,ENGLAND

来源：

HELVETICA CHIMICA ACTA | 1995年 / 78卷 / 05期

关键词：

D O I：

10.1002/hlca.19950780514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal properties of two ferrocene derivatives, substituted by either one or two cholesteryloxycarbonyl units, were investigated. While the monosubstituted ferrocene derivative 1 was found to be non-mesomorphic, the disubstituted ferrocene derivative 2 exhibited a crystal smectic-B phase. This result shows that ferrocene-containing thermotropic liquid crystals, despite the bulkiness of the metallocene core, are not limited to disordered calamitic phases.

引用

页码：1215 / 1218

页数：4

共 13 条

[1] THE SYNTHESIS AND PROPERTIES OF METAL-CONTAINING LIQUID-CRYSTAL SYSTEMS - WHAT CAN THE METAL DO FOR YOU [J].

BRUCE, DW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (20) :2983-2989

[2]

BRUCE DW, 1992, INORG MATER, P405

[3]

Demus D., 1974, FLUSSIGE KRISTALLE T

[4] 1,3-DISUBSTITUTED FERROCENE-CONTAINING THERMOTROPIC LIQUID-CRYSTALS OF FORM (ETA-5-C5H5)FE[(ETA-5-C5H3)-1,3-(CO2C6H4CO2C6H4OCNH2N+1)2] [J].

DESCHENAUX, R ;

SANTIAGO, J ;

GUILLON, D ;

HEINRICH, B .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (05) :679-682

[5]

Deschenaux R., 1995, FERROCENES, P471, DOI 10.1002/9783527615599.ch09

[6]

Elschenbroich C., 1992, ORGANOMETALLICS

[7] TRANSITION-METAL LIQUID-CRYSTALS - ADVANCED MATERIALS WITHIN THE REACH OF THE COORDINATION CHEMIST [J].

ESPINET, P ;

ESTERUELAS, MA ;

ORO, LA ;

SERRANO, JL ;

SOLA, E .

COORDINATION CHEMISTRY REVIEWS, 1992, 117 :215-274

[8] METALLOMESOGENS - METAL-COMPLEXES IN ORGANIZED FLUID PHASES [J].

GIROUDGODQUIN, AM ;

MAITLIS, PM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :375-402

[9]

Gray GW., 1984, SMECTIC LIQUID CRYST

[10] CALAMITIC METALLOMESOGENS - METAL-CONTAINING LIQUID-CRYSTALS WITH RODLIKE SHAPES [J].

HUDSON, SA ;

MAITLIS, PM .

CHEMICAL REVIEWS, 1993, 93 (03) :861-885

← 1 2 →