ION-EXCHANGEABLE LAYERED NIOBATES AS PHOTOCATALYSTS

被引：58

作者：

DOMEN, K ^{[1
]}

EBINA, Y ^{[1
]}

SEKINE, T ^{[1
]}

TANAKA, A ^{[1
]}

KONDO, J ^{[1
]}

HIROSE, C ^{[1
]}

机构：

[1] NIKON CO,SAGAMIHARA 228,JAPAN

来源：

CATALYSIS TODAY | 1993年 / 16卷 / 3-4期

关键词：

D O I：

10.1016/0920-5861(93)80088-I

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Silica pillared-niobates were prepared from a, so called, layered perovskite, KCa2Nb3O10, by using alkylammonium ions as swelling reagents. A product with the interlayer spacing expanded by ca. 1.2 nm and the BET surface area of ca. 200 m2/g was obtained when an octylammonium intercalated precursor was used. The photocatalytic activities of these silica pillared-niobates were compared with those of the original KCa2Nb3O10 and the proton-exchanged derivative. It was revealed that silica pillared-niobates showed a high and characteristic photocatalytic activity.

引用

页码：479 / 486

页数：8

共 6 条

[1] A NOVEL SERIES OF PHOTOCATALYSTS WITH AN ION-EXCHANGEABLE LAYERED STRUCTURE OF NIOBATE
DOMEN, K
YOSHIMURA, J
SEKINE, T
TANAKA, A
ONISHI, T
[J]. CATALYSIS LETTERS, 1990, 4 (4-6) : 339 - 343
[2] NICKEL-LOADED K4NB6O17 PHOTOCATALYST IN THE DECOMPOSITION OF H2O INTO H-2 AND O-2 - STRUCTURE AND REACTION-MECHANISM
KUDO, A
SAYAMA, K
TANAKA, A
ASAKURA, K
DOMEN, K
MARUYA, K
ONISHI, T
[J]. JOURNAL OF CATALYSIS, 1989, 120 (02) : 337 - 352
[3] PREPARATION OF MOLECULAR-SIEVES FROM DENSE, LAYERED METAL-OXIDES
LANDIS, ME
AUFDEMBRINK, BA
CHU, P
JOHNSON, ID
KIRKER, GW
RUBIN, MK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) : 3189 - 3190
[4] PHOTOCATALYTIC DECOMPOSITION OF WATER OVER PLATINUM-INTERCALATED K4NB6O17
SAYAMA, K
TANAKA, A
DOMEN, K
MARUYA, K
ONISHI, T
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (03) : 1345 - 1348
[5] PHOTOCATALYTIC DECOMPOSITION OF WATER OVER A NI-LOADED RB4NB6O17 CATALYST
SAYAMA, K
TANAKA, A
DOMEN, K
MARUYA, K
ONISHI, T
[J]. JOURNAL OF CATALYSIS, 1990, 124 (02) : 541 - 547
[6] YOSHIMURA J, UNPUB J PHYS CHEM

← 1 →