KINETIC RESOLUTION OF RACEMIC CARBOXYLIC-ACIDS AND ALCOHOLS WITH HOMOCHIRAL ALCOHOLS AND CARBOXYLIC-ACIDS, RESPECTIVELY, AND THE MUKAIYAMA OR PALOMO REAGENTS

被引：30

作者：

MAZON, A

NAJERA, C

YUS, M

HEUMANN, A

机构：

[1] UNIV ALICANTE,DEPT QUIM ORGAN,APDO 99,E-03080 ALICANTE,SPAIN

[2] UNIV AIX MARSEILLE,CTR ST JEROME,ENSSPICAM,URA 1410,F-13013 MARSEILLE,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 11期

关键词：

D O I：

10.1016/0957-4166(92)80022-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Mukaiyama and Palomo reagents have been used for the kinetic resolution of racemic carboxylic acids or alcohols with homochiral alcohols or carboxylic acids, respectively, in the presence of triethylamine. Thus, enantiomerically enriched carboxylic acids (e.e.<68%), alcohols (e.e.<41%) or diastereoisomerically enriched esters (d.e.<84%) are obtained.

引用

页码：1455 / 1466

页数：12

共 21 条

[11] LAURENTDIENZEID.E, 1967, B SOC CHIM FR, P1995
[12] KINETIC RESOLUTION OF RACEMIC ALLYLIC ALCOHOLS BY ENANTIOSELECTIVE EPOXIDATION - A ROUTE TO SUBSTANCES OF ABSOLUTE ENANTIOMERIC PURITY
MARTIN, VS
WOODARD, SS
KATSUKI, T
YAMADA, Y
IKEDA, M
SHARPLESS, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (20) : 6237 - 6240
[13] MORRISON JD, 1983, ASYMMETRIC SYNTHESIS, V1, P6
[14] CONVENIENT METHOD FOR SYNTHESIS OF CARBOXYLIC ESTERS
MUKAIYAMA, T
USUI, M
SHIMADA, E
SAIGO, K
[J]. CHEMISTRY LETTERS, 1975, (10) : 1045 - 1048
[15] NEW SYNTHETIC REACTIONS BASED ON THE ONIUM SALTS OF AZA-ARENES
MUKAIYAMA, T
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (10): : 707 - 721
[16] RUCHART C, 1984, CHEM BER, V117, P3457
[17] 1990, FLUKA CHEM BIOCHEMIC
[18] 1982, DICT ORGANIC COMPOUN
[19] 1989, HDB CHEM PHYSICS
[20] 1992, ALDRICH CATALOGUE HD

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