Crystal structure of bis(2-amino-5-chloropyridinium) tetrachloridocobaltate(II)

被引：9
|
作者：
Mghandef, Marwa [1 ]
Boughzala, Habib [1 ]
机构：
[1] Univ Tunis El Manar, Fac Sci Tunis, Lab Mat & Cristallochim, Tunis 2092, Tunisia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; cobalt(II) complex; 2-amino-5-chloropyridine; hydrogen bonding;
D O I：
10.1107/S2056989015007707
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title salt, (C5H6ClN2)(2)[CoCl4], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C5H6ClN2)(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) angstrom] that are nearly perpendicular to each other [dihedral angle = 84.12 (7)degrees]. They are bonded through N-H center dot center dot center dot Cl hydrogen bonds to distorted [CoCl4](2-) tetrahedra, leading to the formation of undulating layers parallel to (100). The structure is isotypic with the Zn analogue [Kefi et. al (2011). Acta Cryst. E67, m355-m356.]
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收藏
页码：555 / +
页数：7
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