EFFECT OF POLYMER MICROSTRUCTURE ON SOLUBILITY CHARACTERISTICS AND INTERACTIONS

被引：1
|
作者：
SAKELLARIOU, P
ABRAHAM, MH
机构：
[1] ICI PAINTS, SLOUGH, BERKS, ENGLAND
[2] UCL, DEPT CHEM, LONDON, ENGLAND
来源：
COLLOID AND POLYMER SCIENCE | 1994年 / 272卷 / 12期
关键词：
POLYBUTADIENE; MICROSTRUCTURE; SOLUBILITY; INTERACTIONS; SOLVATION CONSTANTS; HYDROGEN BOND ACIDITY; HYDROGEN BOND BASICITY;
D O I：
10.1007/BF00664732
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of polymer microstructure on the solubility characteristics and propensity for interactions of polybutadiene (PBD) has been studied by means of the general solvation equation using data reported by Alessi et al. An increase in the vinyl content from 8% to 69% did not affect the propensity of PBD to interact with pi and n electron pairs and with dipolar - polarisable probes. In contrast, the hydrogen-bond basicity decreased due to steric hindrance from the alkene side group.
引用
收藏
页码：1633 / 1636
页数：4
相关论文
共 50 条
  • [31] Effect of nanoimprint on the elastic modulus of polymer microstructure
    Tian, Ye
    Pang, Xiangchao
    Tang, Bin
    Cheng, Xing
    MATERIALS LETTERS, 2019, 255
  • [32] SOLUBILITY PROPERTIES IN POLYMERS AND BIOLOGICAL MEDIA .10. THE SOLUBILITY OF GASEOUS SOLUTES IN POLYMERS, IN TERMS OF SOLUTE POLYMER INTERACTIONS
    ABRAHAM, MH
    GRELLIER, PL
    MCGILL, RA
    DOHERTY, RM
    KAMLET, MJ
    HALL, TN
    TAFT, RW
    CARR, PW
    KOROS, WJ
    POLYMER, 1987, 28 (08) : 1363 - 1369
  • [33] Effect of organic polymer addition on the microstructure of magnetite-polymer hybrid
    Kuwahara, Y.
    Miyazaki, T.
    Kawashita, M.
    BIOCERAMICS 24, 2013, 529-530 : 453 - +
  • [34] The Effect of Redox Potential and Metal Solubility on Oxidative Polymer Degradation
    Levitt, David B.
    Slaughter, Will
    Pope, Gary A.
    Jouenne, Stephane
    SPE RESERVOIR EVALUATION & ENGINEERING, 2011, 14 (03) : 287 - 298
  • [35] Internal Microstructure Dictates Interactions of Polymer-grafted Nanoparticles in Solution
    Gury, Leo
    Kamble, Samruddhi
    Parisi, Daniele
    Zhang, Jianan
    Lee, Jaejun
    Abdullah, Ayesha
    Matyjaszewski, Krzysztof
    Bockstaller, Michael R.
    Vlassopoulos, Dimitris
    Fytas, George
    MACROMOLECULES, 2021, 54 (15) : 7234 - 7243
  • [36] Effect of glycerol on the interactions and solubility of bovine pancreatic trypsin inhibitor
    Farnum, M
    Zukoski, C
    BIOPHYSICAL JOURNAL, 1999, 76 (05) : 2716 - 2726
  • [37] Effect of Asphaltene Characteristics on Its Solubility and Overall Stability
    Prakoso, Andreas
    Punase, Abhishek
    Rogel, Estrella
    Ovalles, Cesar
    Hascakir, Berna
    ENERGY & FUELS, 2018, 32 (06) : 6482 - 6487
  • [38] Effect of donor characteristics on the solubility of a substitutional solute in crystals
    Masharov, SI
    Masharov, GS
    PHYSICS OF METALS AND METALLOGRAPHY, 2003, 95 (01): : 26 - 30
  • [39] THE PREDICTION OF POLYMER SOLUBILITY
    ASKADSKII, AA
    MATVEEV, II
    DOKLADY AKADEMII NAUK SSSR, 1986, 290 (01): : 135 - 139
  • [40] Control of polymer-electrode interactions:: the effect of leaving group on the optical properties and device characteristics of EHPPV
    Lo, SC
    Pålsson, LO
    Kilitziraki, M
    Burn, PL
    Samuel, IDW
    JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (09) : 2228 - 2231
12345