REACTION OF PENTACARBONYL(METHYLPYRROLIDINOCARBENE)CHROMIUM(0) WITH ALDEHYDES - A NEW ENTRY TO PENTACARBONYL(ALKENYLPYRROLIDINOCARBENE)CHROMIUM(0)

被引：0
|
作者：
BALDOLI, C [1 ]
DELBUTTERO, P [1 ]
LICANDRO, E [1 ]
MAIORANA, S [1 ]
PAPAGNI, A [1 ]
ZANOTTIGEROSA, A [1 ]
机构：
[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,VIA GOLGI 19,I-20133 MILAN,ITALY
来源：
SYNLETT | 1993年 / 12期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The conjugate base of pentacarbonyl(methylpyrrolidinocarbene)chromium(0) (1) easily reacts with aldehydes, yielding aldol products (2). The latter are converted into the corresponding pentacarbonyl(alkenylpyrrolidinocarbene) complexes with high E selection under very mild conditions.
引用
收藏
页码：935 / 936
页数：2
相关论文
共 50 条
  • [21] CRYSTAL STRUCTURE OF PENTACARBONYL-(2,3-DIPHENYLCYCLOPROPENYLIDENE)CHROMIUM(0)
    HUTTNER, G
    SCHELLE, S
    MILLS, OS
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (07) : 515 - &
  • [22] SYNTHESIS OF AMINO-BETA-LACTAMS BY THE PHOTOLYTIC REACTION OF IMINES WITH PENTACARBONYL[(DIBENZYLAMINO)CARBENE]CHROMIUM(0)
    BOREL, C
    HEGEDUS, LS
    KREBS, J
    SATOH, Y
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (04) : 1101 - 1105
  • [23] SYNTHESIS OF PENTACARBONYL(2,3-DIALKOXYCYCLOPROPENYLIDENE)CHROMIUM(0), MOLYBDENUM(0), AND TUNGSTEN(0) COMPLEXES BY REACTION OF METAL HEXACARBONYLS WITH LITHIUM ETHOXYACETYLIDE
    JUNEAU, KN
    HEGEDUS, LS
    ROEPKE, FW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) : 4762 - 4765
  • [24] SYNTHESIS OF NAPHTHOL SKELETON FROM PENTACARBONYL[METHOXY(PHENYL)CARBENE]CHROMIUM(0) AND TOLAN
    DOTZ, KH
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (09): : 644 - 645
  • [25] KINETICS OF PROTON-TRANSFER REACTIONS OF (METHOXYBENZYLCARBENE)-PENTACARBONYL CHROMIUM(0) WITH KOH AND AMINES
    BERNASCONI, CF
    SUN, WT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 268 - ORGN
  • [26] TRANSITION-METAL CARBENE COMPLEXES .93. PENTACARBONYL(DIARYLCARBENE) COMPLEXES OF CHROMIUM(0) AND TUNGSTEN(0)
    FISCHER, EO
    HELD, W
    KREISSL, FR
    FRANK, A
    HUTTNER, G
    CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (02): : 656 - 666
  • [27] SULFENAMIDES AS LIGANDS IN TRANSITION-METAL CHEMISTRY PENTACARBONYL(SULFENAMIDE)CHROMIUM(0) COMPLEXES
    DIAZ, C
    CUEVAS, J
    GONZALEZ, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 592 (01): : 7 - 16
  • [28] TRANSITION-METAL CARBENE COMPLEXES .102. PENTACARBONYL(ACYLOXYORGANYLCARBENE) COMPLEXES OF CHROMIUM(0) AND TUNGSTEN(0)
    FISCHER, EO
    SELMAYR, T
    KREISSL, FR
    CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (08): : 2947 - 2955
  • [29] PENTACARBONYL(ACETOXYORGANYLCARBENE) COMPLEXES OF CHROMIUM(0) AND TUNGSTEN(0) - TRANSITION-METAL CARBENE COMPLEXES .104.
    FISCHER, EO
    SELMAYR, T
    KREISSL, FR
    MONATSHEFTE FUR CHEMIE, 1977, 108 (04): : 759 - 765
  • [30] PENTACARBONYL(DIMESITYLGERMANEDIYL)CHROMIUM(O)
    JUTZI, P
    STEINER, W
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (09): : 639 - 639
12345