N-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl}azanide trihloridostannate(II)

被引：0
|
作者：
Ma, Xiaoli [1 ]
Sun, Shuai [1 ]
Hao, Pengfei [1 ]
Yang, Ying [2 ]
Yang, Zhi [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
[2] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1107/S1600536812014729
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, (C28H43N2)[SnCl3], two pairs of molecular species are present in the asymmetric unit. The employed a-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N-C=1.264 (4) and 1.516 (4) angstrom]. One of the C=N double bonds was oxidized to C-N, which is consistent with the bond length of 1.516 (4) angstrom. Meanwhile Sn-IV was reduced to Sn-II. The (SnCl)(3)(-) anion is trigonal-pyramidal. In the crystal, molecules are linked by C-H center dot center dot center dot Cl, N-H center dot center dot center dot Cl, N-H center dot center dot center dot N and C-H center dot center dot center dot N bonds. The crystal studied was twinned by pseudo-merohedry.
引用
收藏
页码：N719 / +
页数：16
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