ELECTRICAL-CONDUCTIVITY ANOMALY IN BINARY-LIQUID MIXTURES NEAR THE CRITICAL-POINT

被引:2
|
作者
CHATTERJEE, AK
LAHIRI, D
GHOSH, R
机构
[1] Department of Physics, North Bengal University, Dist. Darjeeling
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1992年 / 31卷 / 07期
关键词
CRITICAL TEMPERATURE; CRITICAL CONDUCTIVITY; CRITICAL EXPONENT; CONCENTRATION FLUCTUATION; FREQUENCY MATCHING EFFECT;
D O I
10.1143/JJAP.31.2151
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electrical conductivity (sigma) of the three binary liquid mixtures (a) CH3OH + CS2, (b) C6H5NO2 + C6H14 and (c) C6H5NH2 + C6H12 has been determined at various temperatures starting from the one-phase region down to critical temperature (T(c)) at 400 kHz. It is observed that the critical exponent 0 of the conductivity singularity near T(c) has no appreciable dependence upon the operating frequency. Thus any contribution from dielectric dispersion to the electric conductivity is negligible. Therefore it is concluded that there is a singular contribution to the electrical conductivity which is characterised by an exponent THETA = 0.72 in binary liquid systems.
引用
收藏
页码:2151 / 2154
页数:4
相关论文
共 10 条
  • [1] Thermodynamics of multicomponent mixtures near the liquid-vapor critical point
    M. Yu. Belyakov
    V. P. Voronov
    E. E. Gorodetskii
    B. A. Grigor’ev
    V. A. Deshabo
    V. I. Kosov
    V. D. Kulikov
    V. N. Kur’yakov
    I. K. Yudin
    D. I. Yudin
    High Temperature, 2012, 50 : 479 - 487
  • [2] Thermodynamics of multicomponent mixtures near the liquid-vapor critical point
    Belyakov, M. Yu.
    Voronov, V. P.
    Gorodetskii, E. E.
    Grigor'ev, B. A.
    Deshabo, V. A.
    Kosov, V. I.
    Kulikov, V. D.
    Kur'yakov, V. N.
    Yudin, I. K.
    Yudin, D. I.
    HIGH TEMPERATURE, 2012, 50 (04) : 479 - 487
  • [3] Gravity influence on internal field of liquid near the critical point
    Alekhin, A. D.
    JOURNAL OF MOLECULAR LIQUIDS, 2006, 127 (1-3) : 62 - 64
  • [4] Predicting the gas-liquid critical temperature of binary mixtures based on the quantitative structure property relationship
    Zhou, Lulu
    Wang, Beibei
    Jiang, Juncheng
    Pan, Yong
    Wang, Qingsheng
    CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 2017, 167 : 190 - 195
  • [5] Excess molar volume and viscosity of isobutyric acid plus water binary mixtures near and far away from the critical temperature
    Ouerfelli, N
    Bouanz, M
    JOURNAL OF SOLUTION CHEMISTRY, 2006, 35 (01) : 121 - 137
  • [6] Density Response and Equilibration in a Pure Fluid Near the Liquid-Vapor Critical Point: 3He
    Andrei B. Kogan
    Horst Meyer
    Journal of Low Temperature Physics, 1998, 112 : 419 - 449
  • [7] The composition dependence of critical temperatures (liquid-vapor) of 1,3,5-trimethyladamantane-1,3-dimethyladamantane binary mixtures
    Sarkisova, V. S.
    Nazmutdinov, A. G.
    Alekina, E. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (06) : 1048 - 1050
  • [8] The composition dependence of critical temperatures (liquid-vapor) of 1,3,5-trimethyladamantane—1,3-dimethyladamantane binary mixtures
    V. S. Sarkisova
    A. G. Nazmutdinov
    E. V. Alekina
    Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 : 1048 - 1050
  • [9] Plotting of phase (vapor-liquid) transition surface near the critical point out of data from isochoric experiment. Experimental procedure
    Vostrikov, Sergey V.
    Pimerzin, Andrey A.
    Konnova, Maria E.
    Sarkisova, Victoria S.
    FLUID PHASE EQUILIBRIA, 2018, 462 : 118 - 129
  • [10] Simple approach to approximate predictions of the vapor-liquid equilibrium curve near the critical point and its application to Lennard-Jones fluids
    Staskiewicz, B.
    Okrasinski, W.
    PHYSICS LETTERS A, 2012, 376 (21) : 1721 - 1730