NOVEL PERFLUOROALKYLATION OF ALKENES WITH PERFLUOROALKANESULPHONYL CHLORIDES CATALYZED BY A RUTHENIUM(II) COMPLEX

被引：104

作者：

KAMIGATA, N ^{[1
]}

FUKUSHIMA, T ^{[1
]}

TERAKAWA, Y ^{[1
]}

YOSHIDA, M ^{[1
]}

SAWADA, H ^{[1
]}

机构：

[1] NIPPON OIL & FATS CO LTD,TSUKUBA RES LAB,TSUKUBA,IBARAKI 30026,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 03期

关键词：

D O I：

10.1039/p19910000627

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The perfluoroalkylation of acyclic and cyclic alkenes by perfluoroalkanesulphonyl chlorides 1 has been investigated in the presence of a ruthenium(II) catalyst. The addition reactions proceeded smoothly, with extrusion of sulphur dioxide, in alkenes possessing either an electron-donating or an electron-withdrawing group, at 120-degrees-C to give the corresponding chloroperfluoroalkylated compounds in high yield.

引用

页码：627 / 633

页数：7

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