A MASS-SPECTROMETRIC INVESTIGATION OF CXNO2 (X = 1,2) IONS AND NEUTRALS

被引：20

作者：

SULZLE, D ^{[1
]}

OBANNON, PE ^{[1
]}

SCHWARZ, H ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 01期

关键词：

INTERSTELLAR CHEMISTRY; HETEROCUMULENES; NEUTRALIZATION-REIONIZATION MASS SPECTROMETRY;

D O I：

10.1002/cber.19921250144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isomeric [C2,N,O2]+ ions OCNCO+, OCCNO+, and NCCO2 have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization-reionization mass spectra. The open-shell neutrals formed in the neutralization step undergo facile unimolecular decomposition. A recovery signal is obtained only for OCCNO.

引用

页码：279 / 283

页数：5

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