A MASS-SPECTROMETRIC INVESTIGATION OF CXNO2 (X = 1,2) IONS AND NEUTRALS

被引：20
|
作者：
SULZLE, D [1 ]
OBANNON, PE [1 ]
SCHWARZ, H [1 ]
机构：
[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 01期
关键词：
INTERSTELLAR CHEMISTRY; HETEROCUMULENES; NEUTRALIZATION-REIONIZATION MASS SPECTROMETRY;
D O I：
10.1002/cber.19921250144
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The isomeric [C2,N,O2]+ ions OCNCO+, OCCNO+, and NCCO2 have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization-reionization mass spectra. The open-shell neutrals formed in the neutralization step undergo facile unimolecular decomposition. A recovery signal is obtained only for OCCNO.
引用
收藏
页码：279 / 283
页数：5
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