STEREOCHEMISTRY OF ASYMMETRIC SILICON .13. GENERAL DEMONSTRATION OF STEREOCHEMISTRY CROSSOVER FOR REACTIONS INVOLVING CERTAIN LEAVING GROUPS AND ALKOXIDE REAGENTS

被引：16

作者：

SOMMER, LH

FUJIMOTO, H

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereochemistry crossover from retention to inversion of configuration (or vice versa) in individual reaction series involving alkoxide reagents is reported for the leaving groups OPh, SMe, and F. The reactant is R3Si*X (R3Si* is α-naphthylphenylmethylsilyl). Mechanistic implications of this work are discussed and further support for the Sni-Si and Sn2-Si mechanisms is adduced. © 1969, American Chemical Society. All rights reserved.

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页码：7040 / &

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