CONSISTENT VALUES OF RATE PARAMETERS IN FREE-RADICAL POLYMERIZATION SYSTEMS

被引：168

作者：

BUBACK, M

GARCIARUBIO, LH

GILBERT, RG

NAPPER, DH

GUILLOT, J

HAMIELEC, AE

HILL, D

ODRISCOLL, KF

OLAJ, OF

SHEN, JC

SOLOMON, D

MOAD, G

STICKLER, M

TIRRELL, M

WINNIK, MA

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

[2] UNIV GOTTINGEN,INST PHYS CHEM,D-3400 GOTTINGEN,FED REP GER

[3] UNIV QUEENSLAND,DEPT PHYS CHEM,ST LUCIA,QLD 4067,AUSTRALIA

[4] UNIV WATERLOO,DEPT CHEM ENGN,WATERLOO N2L 3G1,ONTARIO,CANADA

[5] VIENNA UNIV,INST PHYS CHEM,A-1090 VIENNA,AUSTRIA

[6] JILIN UNIV,DEPT CHEM,CHANGCHUN,PEOPLES R CHINA

[7] CSIRO,DIV APPL ORGAN CHEM,MELBOURNE,VIC 3001,AUSTRALIA

[8] ROHM GMBH,D-6100 DARMSTADT,FED REP GER

[9] UNIV MINNESOTA,DEPT CHEM ENGN & MAT SCI,MINNEAPOLIS,MN 55455

[10] UNIV TORONTO,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA

[11] MCMASTER UNIV,DEPT CHEM ENGN,HAMILTON L8S 4L7,ONTARIO,CANADA

[12] CNRS,MAT ORGAN LAB,F-69390 VERNAISON,FRANCE

[13] UNIV S FLORIDA,DEPT CHEM & MECH ENGN,TAMPA,FL 33620

来源：

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS | 1988年 / 26卷 / 07期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - MONOMERS - Polymerization - POLYMETHYL METHACRYLATE - Synthesis - POLYSTYRENES - Synthesis;

D O I：

10.1002/pol.1988.140260704

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Inspection of tabulated rate coefficients shows that there is a wide divergence in literature values of kinetic parameters for free radical polymerizations under ostensibly the same conditions. This communication is an attempt to initiate a solution to this problem by seeing if agreement exists on the values of some fundamental kinetic parameters for simple monomers, determined using quite different experimental techniques (e. g. , comparing bulk versus emulsion data, 'classical' rate studies versus ESR studies, etc. ) 17 Refs.

引用

页码：293 / 297

页数：5

共 22 条

[1] KINETICS OF EMULSION POLYMERIZATION OF METHYL-METHACRYLATE [J].