SYNTHESIS, CHARACTERIZATION, AND SOLID-STATE STRUCTURES OF THE 14-ELECTRON OPEN METALLOCENES M[1,5-(ME(3)SI)(2)C5H5](2) (M=TI OR ZR)

被引：22

作者：

GEDRIDGE, RW ^{[1
]}

ARIF, AM ^{[1
]}

ERNST, RD ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

TITANIUM; ZIRCONIUM; OPEN METALLOCENES; X-RAY CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05624-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of titanium(II) or zirconium(IV) chlorides with two or four equivalents of K[1,5-(Me(3)Si)(2)C5H5], respectively, lead to the diamagnetic 14-electron M[1,5-(Me(3)Si)(2)C5H5](2) complexes. Both have been characterized analytically, spectroscopically, and through single crystal X-ray diffraction studies.

引用

页码：95 / 100

页数：6

共 36 条

[31] Bridging cyclopentadienyl M-Sn(IV) bonded polymetallic complexes:: X-ray crystal structures of [(Me2SnCl)(CO)3MoC5H4C(O)CH2]2•CH2Cl2 and [(Ph3Sn)(CO)3WC5H4C(O)CH2]2•3H2O
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[32] Synthesis, structural characterization and reactivity of new tin bridged ansa-bis(cyclopentadiene) compounds:: X-ray crystal structures of Me2Sn(C5Me4R-1)2 (R = H, SiMe3)
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[33] Syndiospecific polymerization of propylene: 2-substituted and 2,7-substituted metallocene complex of the (C(13)H(8-n)R(n)CR(n)(')C5H4)MCl(2) (n=1,2; R=alkoxy, alkyl, hal; R(')=Me, Ph; M=Zr, Hf)
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (01) : 39 - 54
[34] Ethylene polymerization and ethylene/1-octene copolymerization using group 4 half-metallocenes containing aryloxo ligands, Cp*MCl2(OAr) [M = Ti, Zr, Hf; Ar = O-2,6-R2C6H3, R = tBu, Ph]-MAO catalyst systems
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[35] Synthesis and characterization of two new "pincer" complexes of zinc(II).: The X-ray crystal structures of the five coordinate complexes [ZnCl2{eta3-NN′N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me)
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CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2000, 78 (12): : 1620 - 1626
[36] ALKYLATION VS PROTOLYSIS - ALTERNATIVE APPROACHES IN THE REACTIVITY OF L-HYDROXYCYCLOOCTADIENE(1,5) RHODIUM(I) DIMER WITH METHYL-DERIVATIVES OF TI(IV) - SYNTHESIS, X-RAY CRYSTAL STRUCTURAL-ANALYSIS AND HETEROGENEOUS CATALYTIC TESTING OF THE NOVEL OXO-BRIDGED TITANIUM RHODIUM COMPLEX ((MU-3(RH,RH,TI)-O)4[RH(I)(COD-1,5)]4[TI(IV)((T)C4H9O)2]2)
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) : 131 - 138

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