SYNTHESIS, CHARACTERIZATION, AND SOLID-STATE STRUCTURES OF THE 14-ELECTRON OPEN METALLOCENES M[1,5-(ME(3)SI)(2)C5H5](2) (M=TI OR ZR)

被引：22

作者：

GEDRIDGE, RW ^{[1
]}

ARIF, AM ^{[1
]}

ERNST, RD ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

TITANIUM; ZIRCONIUM; OPEN METALLOCENES; X-RAY CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05624-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of titanium(II) or zirconium(IV) chlorides with two or four equivalents of K[1,5-(Me(3)Si)(2)C5H5], respectively, lead to the diamagnetic 14-electron M[1,5-(Me(3)Si)(2)C5H5](2) complexes. Both have been characterized analytically, spectroscopically, and through single crystal X-ray diffraction studies.

引用

页码：95 / 100

页数：6

共 36 条

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Antiñolo, A
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EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (14) : 2626 - 2632
[22] Facile synthesis and X-ray structures of (η5-C5Me5)Ti(OArF)3 (OArF = OC6F5,OCH2C6F5, and OCH2C6F2H3)
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Do, Youngkyu
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (16) : 3593 - 3598
[23] The first early transition metal perfluorovinyl complexes:: the synthesis of Cp2M(CF=CF2)nX2-n (Cp: η5-C5H5-; M = Ti, Zr; X = Cl or F) and structures of Cp2Ti(CF=CF2)nX2-n (X = Cl, F) via Ti K-edge EXAFS studies
Banger, KK
Brisdon, AK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 582 (02) : 301 - 309
[24] Catalytic systems Me2SiCp*NtBuMX2/(CPh3)(B(C6F5)4) (M = Ti, X = CH3, M = Zr, X = tBu) in copolymerization of ethylene with styrene
Sukhova, TA
Panin, AN
Babkina, ON
Bravaya, NM
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (08) : 1083 - 1093
[25] Synthesis and electrochemical behaviour of σ,η2-acetylide-bridged early-late complexes;: The solid-state structure of [(η5-C5H4SiMe3)2Ti(C≡C-SiMe3)2]Pd(PPh3)
Back, S
Stein, T
Kralik, J
Weber, C
Rheinwald, G
Zsolnai, L
Huttner, G
Lang, H
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 664 (1-2) : 123 - 129
[26] DYNAMIC STEREOCHEMISTRY IN THE TITANOCENE SERIES WITH CENTRAL AND PLANAR CHIRALITY - X-RAY STRUCTURE AND RELATIVE CONFIGURATION OF THE RACEMIC FORM (MP 186-DEGREES-C) OF [(ETA(5)-1-ME-2-(PRC5H3)-PR-I)(ETA(5)-C5H5)TI(2,6-ME(2)C(6)H(3)O)CL]
BESANCON, J
SZYMONIAK, J
MOISE, C
TOUPET, L
TRIMAILLE, B
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 491 (1-2) : 31 - 39
[27] Metal-Stabilized [B8H8]2- Derivatives with Dodecahedral Structure in the Solid and Solution States: [(Cp2MBH3)2B8H6] (Cp=η5-C5H5; M=Zr (1-Zr) and Hf (1-Hf)).
Kar, Sourav
Bairagi, Subhash
Joshi, Gaurav
Jemmis, Eluvathingal D.
Ghosh, Sundargopal
CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (63) : 15634 - 15637
[28] PREPARATION AND CRYSTAL-STRUCTURES OF THE COMPLEXES (ETA(5)-C(5)H(3)ME-CME(2)-ETA(5)-C13H8)MCL(2) (M=ZR OR HF) - MECHANISTIC ASPECTS OF THE CATALYTIC FORMATION OF A SYNDIOTACTIC-ISOTACTIC STEREOBLOCK-TYPE POLYPROPYLENE
RAZAVI, A
ATWOOD, JL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 497 (1-2) : 105 - 111
[29] Synthesis and characterization of oxo- and thiophosphorylcyclopentadienyl Ti(IV) thiolate complexes.: Crystal structures of [(η5-C5H4P(S)Ph2)(η5-C5H4SiMe3)TiCl2] and [(η5-C5H4P(S)Ph2)2Ti(SPh)2]•C4H10O
Delgado, E
Garcia, MA
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Mansilla, N
Martinez-Cruz, LA
Tornero, J
Torres, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 560 (1-2) : 27 - 33
[30] Preparation and crystal structures of the complexes (η5-C5H3TMS-CMe2-η5C13H8)MCl2 and [3,6-ditButC13H6-SiMe2-NtBu]MCl2 (M = Hf, Zr or Ti):: mechanistic aspects of the catalytic formation of a isotactic-syndiotactic stereoblock-type polypropylene
Razavi, A
Thewalt, U
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 621 (1-2) : 267 - 276

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