SYNTHESIS, CHARACTERIZATION, AND SOLID-STATE STRUCTURES OF THE 14-ELECTRON OPEN METALLOCENES M[1,5-(ME(3)SI)(2)C5H5](2) (M=TI OR ZR)

被引：22
|
作者：
GEDRIDGE, RW [1 ]
ARIF, AM [1 ]
ERNST, RD [1 ]
机构：
[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
TITANIUM; ZIRCONIUM; OPEN METALLOCENES; X-RAY CRYSTAL STRUCTURE;
D O I：
10.1016/0022-328X(95)05624-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of titanium(II) or zirconium(IV) chlorides with two or four equivalents of K[1,5-(Me(3)Si)(2)C5H5], respectively, lead to the diamagnetic 14-electron M[1,5-(Me(3)Si)(2)C5H5](2) complexes. Both have been characterized analytically, spectroscopically, and through single crystal X-ray diffraction studies.
引用
收藏
页码：95 / 100
页数：6
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