HYDRODYNAMICALLY INDUCED FORMATION OF CELLULOSE FIBERS .3. COAGULATION OF DROPLETS OF CELLULOSE SOLUTION IN EXTENSIONAL FLOW

In the reported investigation, the formation of cellulose fibers by coagulation of drops of cellulose solution in extensional flow was studied theoretically and experimentally. In the theory, which applies for slow-motion conditions, homogeneity of the drop is assumed. The drop deforms according to a previously established deformation mechanism and becomes solid when a critial concentration of coagulant is reached at a certain position inside the drop. The theoretical predictions for the variation of fiber length with various parameters were tested experimentally in a four-roller mill for cellulose/dimethyl sulfoxide/paraformaldehyde with glycerol as coagulant. In agreement with the theoretical predictions, it was found that fiber length increases with shear rate and original droplet size, but decreases with the diffusion coeffiecient of the coagulant in the cellulose solution.