SYNTHESIS AND CHARACTERIZATION OF PHOTO-CROSS-LINKABLE SMALL-MOLECULE AND HIGH-POLYMERIC PHOSPHAZENES BEARING CINNAMATE GROUPS

被引：40

作者：

ALLCOCK, HR

CAMERON, CG

机构：

[1] Department of Chemistry, The Pennsylvania State University, Pennsylvania 16802, University Park

来源：

MACROMOLECULES | 1994年 / 27卷 / 12期

关键词：

D O I：

10.1021/ma00090a002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cyclic trimeric and high-polymeric phosphazenes bearing cinnamate groups were synthesized and characterized. Cyclic trimers with the general formula N3P3RyRx' where R = OC6H4OC(O)CH=CHPh, R' - OCH2CF3 (y = 1, x = 5 and y = 6, x = 0), and R = (OCH2CH2)2OC(O)CH=CHPh (y = 1, x = 5 and y = 6, x = 0) were synthesized. Also prepared were high-polymeric phosphazenes [NPR(x)R(y)']n, where R = OC6H4OC(O)CH=CHPh, R' = OCH2CF3 (y = x = 1 d y = 0, x = 2) and R = (OCH2CH2)2OC(O)CH = CHPh (y = x = 1 and y = 0, x = 2). The photo-cross-linking of a representative polymer was studied by UV spectroscopy.

引用

页码：3125 / 3130

页数：6

共 24 条

[11] GLERIA M, 1992, J INORG ORGANOMET P, V2, P329
[12] JUNG ME, 1977, J ORG CHEM, V42, P3772
[13] PHOTO-CROSS-LINKABLE LIQUID-CRYSTALLINE SIDE-CHAIN POLYSILOXANES
KELLER, P
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (01) : 3 - 4
[14] FUNCTIONALIZATION OF PHOSPHAZENES .1. SYNTHESIS OF PHOSPHAZENE MATERIALS CONTAINING HYDROXYL-GROUPS
MEDICI, A
FANTIN, G
PEDRINI, P
GLERIA, M
MINTO, F
[J]. MACROMOLECULES, 1992, 25 (10) : 2569 - 2574
[15] PHOTOCHEMISTRY OF POLYMERIC SYSTEMS .8. PHOTO-CROSSLINKING OF POLYSILOXANES INCLUDING CINNAMIC, FURACRYLIC OR ALPHA-CYANO BETA-STYRYLACRYLIC ESTER GROUPS - A COMPARATIVE-STUDY
MERCIER, R
COQUERET, X
LABLACHECOMBIER, A
LOUCHEUX, C
[J]. EUROPEAN POLYMER JOURNAL, 1988, 24 (07) : 639 - 645
[16] Minsk L. M., 1954, US Pat., Patent No. [2 690 966, 2690966]
[17] MINSK LM, 1959, J APPL POLYM SCI, V11, P302
[18] MIYASHITA M, 1977, J ORG CHEM, V42, P3761
[19] ULTRAVIOLET RADIATION-INDUCED CROSS-LINKING OF POLY[BIS(2-(2-METHOXYETHOXY)ETHOXY)PHOSPHAZENE]
NELSON, CJ
COGGIO, WD
ALLCOCK, HR
[J]. CHEMISTRY OF MATERIALS, 1991, 3 (05) : 786 - 787
[20] NISHIKUBO T, 1982, MAKROMOL CHEM-RAPID, V3, P377

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