AN EFFECTIVE HARD-SPHERE MODEL OF THE NON-NEWTONIAN VISCOSITY OF STABLE COLLOIDAL DISPERSIONS - COMPARISON WITH FURTHER DATA FOR STERICALLY STABILIZED LATICES AND WITH DATA FOR MICROGEL PARTICLES

被引：46

作者：

BUSCALL, R ^{[1
]}

机构：

[1] ICI PLC,CORP COLLOID SCI GRP,RUNCORN WA7 4QE,CHESHIRE,ENGLAND

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1994年 / 83卷 / 01期

关键词：

DISPERSION RHEOLOGY; LATEX VISCOSITY; MICROGEL VISCOSITY;

D O I：

10.1016/0927-7757(93)02652-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An effective hard-sphere model for the non-Newtonian viscosity of soft-sphere dispersions is used to analyse recent experimental data for small latices and microgels. The approach is shown to scale the concentration and shear stress dependence of the viscosity well. The scaling is performed in terms of an apparent, interparticle pair potential.

引用

页码：33 / 42

页数：10

共 15 条

[1] THEORIES OF LIQUIDS [J].

BARKER, JA ;

HENDERSON, D .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1972, 23 :439-+

[2]

BLATCHFORD J, 1969, J PHYS CHEM-US, V73, P1062

[3] EFFECT OF ELECTROLYTE CONTENT ON SYNTHETIC LATEX FLOW BEHAVIOR [J].

BRODNYAN, JG ;

KELLEY, EL .

JOURNAL OF COLLOID SCIENCE, 1965, 20 (01) :7-&

[4]

BRODNYAN JG, 1964, J COLLOID INTERF SCI, V19, P448

[5] COMMENT ON THE INTERACTION FORCES OF POLYMER-COATED SURFACES [J].

BUSCALL, R .

LANGMUIR, 1992, 8 (08) :2077-2079

[6] EFFECT OF LONG-RANGE REPULSIVE FORCES ON THE VISCOSITY OF CONCENTRATED LATTICES - COMPARISON OF EXPERIMENTAL-DATA WITH AN EFFECTIVE HARD-SPHERE MODEL [J].

BUSCALL, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (09) :1365-1370

[7] HARD-SPHERE COLLOIDAL DISPERSIONS - VISCOSITY AS A FUNCTION OF SHEAR RATE AND VOLUME FRACTION [J].

DEKRUIF, CG ;

VANLERSEL, EMF ;

VRIJ, A ;

RUSSEL, WB .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (09) :4717-4725

[8]

FRITH WJ, 1986, THESIS KATHOLIEKE U

[9] THE RHEOLOGY OF A STERICALLY STABILIZED SUSPENSION AT HIGH-CONCENTRATION [J].

JONES, DAR ;

LEARY, B ;

BOGER, DV .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 150 (01) :84-96

[10]

Krieger I. M., 1972, ADV COLLOID INTERFAC, V3, P111, DOI DOI 10.1016/0001-8686(72)80001-0

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