3 COMPONENT REACTIONS .20. METHOXYMERCURATION OF CYCLOHEXA-1,4-DIENES

被引:2
|
作者
BEGER, J [1 ]
THOMAS, B [1 ]
VOGEL, T [1 ]
LANG, R [1 ]
机构
[1] TECH UNIV DRESDEN,CHEM ABT,O-8027 DRESDEN,GERMANY
来源
JOURNAL FUR PRAKTISCHE CHEMIE | 1991年 / 333卷 / 03期
关键词
D O I
10.1002/prac.19913330310
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The methoxymercuration of several cyclohexa-1,4-dienes leads to insoluble mixtures of mono- and bismercuricompounds 2-4 and 5-7. After reduction with NaBH4/NaOH mixtures of methoxycyclohexenes and bismethoxycyclohexanes result. The result of capillary gaschromatographic analyses and n.m.r. spectra allow a semiquantitative evaluation of the reaction pathways.
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页码:447 / 453
页数:7
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