MASS-SPECTRUM OF 2-CYCLOHEXENOL - LOSS OF CH3. AND H. FROM THE MOLECULAR ION

被引：3

作者：

ADLEY, TJ ^{[1
]}

MATTEO, G ^{[1
]}

RYE, RTB ^{[1
]}

机构：

[1] CONCORDIA UNIV, DEPT CHEM, MONTREAL H3G 1M8, QUEBEC, CANADA

来源：

ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 10期

关键词：

D O I：

10.1002/oms.1210141009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl radical and hydrogen atom losses from the molecular ion of 2‐cyclohexenol and deuterium labelled analogues have been studied. For fragmentations occurring in the first field free region, H⋅ loss is a random process, whereas CH3⋅ loss is highly specific involving the C‐1 hydrogen atom and the C‐5 methylene group. A mechanism consistent with these results is proposed. Copyright © 1979 Heyden & Son Ltd

引用

页码：562 / 563

页数：2