VIBRATIONAL-RELAXATION OF NO BY ATOMIC OXYGEN

被引：80
|
作者：
FERNANDO, RP
SMITH, IWM
机构：
[1] Department of Physical Chemistry, University Chemical Laboratories, Cambridge
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 02期
关键词：
D O I：
10.1016/0009-2614(79)85002-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A laser-induced fluorescence method has been used to study the vibrational relaxation of NO by atomic oxygen, i.e. NO(v=1) + O - NO(v=0) + O(2). The NO was excited indirectly by vibrational-vibrational energy transfer from HCI(v=1), these molecules having been prepared using the output from a pulsed HCl chemical laser. The experiments yield: k2=(6.5 ± 0.7) × 10-11 cm3 molecule-1 s-1 at (296 ± 3) K. © 1979.
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页码：218 / 222
页数：5
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