ORGANOMETALLIC COMPLEXES WITH METAL-METAL BONDS .12. TRIMETALLIC CARBENE COMPLEX WITH MO-PT-MO BONDS - PREPARATION AND STRUCTURE OF TRANS-PT(C6H11NC)(C6H11NHCOC2H5)-[MO(CO)3ETA-5-C5H5]2

被引：33
作者：
BRAUNSTEIN, P [1 ]
KELLER, E [1 ]
VAHRENKAMP, H [1 ]
机构：
[1] UNIV FREIBURG,CHEM LAB,D-7800 FREIBURG,FED REP GER
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 02期
关键词：
D O I：
10.1016/S0022-328X(00)94325-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The linear trimetallic title complex is formed from cis-Cl2Pt(CNC6H11)[C(OC)2H5)(NHC6H11)] and NaMoCp(CO)3. It has been characterized by IR-spectral data and by a crystal structure determination. The metal-metal stretching frequency of 156 cm-1 and the PtMo distances of 288.9 pm indicate relatively strong PtMo bonding. © 1979.
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页码：233 / 242
页数：10
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