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ELECTROPHILIC BEHAVIOR OF LITHIATED 1-ALKOXYALKYL AND 1-ALKYLTHIOALKYL SULFONES - REGIOSELECTIVE SYNTHESIS OF ENOL ETHERS AND VINYL SULFIDES
被引：0
|作者：
HABERMANN, AK
JULIA, M
VERPEAUX, JN
ZHANG, D
机构：
[1] ECOLE NORMALE SUPER,DEPT CHIM,CNRS,URA 1686,F-75231 PARIS 05,FRANCE
[2] ECOLE NORMALE SUPER,DEPT CHIM,CNRS,URA 1679,F-75231 PARIS 05,FRANCE
来源：
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE
|
1994年
/
131卷
/
09期
关键词：
SULFONES;
ALKOXYALKYL SULFONES;
CARBENOIDS;
ENOL ETHERS;
HETEROSUBSTITUTED CARBANIONS;
ALKYLTHIOALKYL SULFONES;
VINYL SULFIDES;
D O I：
暂无
中图分类号：
Q5 [生物化学];
Q7 [分子生物学];
学科分类号：
071010 ;
081704 ;
摘要：
The readily available 1-alkoxyalkyl and 1-alkylthioalkyl sulfones display electrophilic behavior when lithiated. For example, both react regioselectively with lithiated alkyl sulfones to give enol ethers and vinyl sulfides, respectively. A series of methyl and tert-butyl enol ethers and vinyl sulfides have been prepared.
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页码：965 / 972
页数：8
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