ENTHALPY OF MIGRATION OF ANION VACANCIES IN SODIUM-CHLORIDE

被引：14

作者：

COOK, JS ^{[1
]}

DRYDEN, JS ^{[1
]}

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY 2006,NEW S WALES,AUSTRALIA

来源：

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS | 1979年 / 12卷 / 20期

关键词：

D O I：

10.1088/0022-3719/12/20/014

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Single crystals of sodium chloride doped with bivalent anions (S 2-) have been prepared. Electric conductivity measurement of these crystals yields an enthalpy of migration ( Delta ha) of anion vacancies in sodium chloride of 1.24+or-0.05 eV. This result is considered to be more reliable than previously published values.

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页码：4207 / 4215

页数：9

相关论文

共 26 条

[1] ELECTRICAL CONDUCTIVITY OF CRYSTALLINE SODIUM CHLORIDE [J].

ALLNATT, AR ;

PANTELIS, P ;

SIME, SJ .

JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS, 1971, 4 (13) :1778-+

[2] AC POLARIZATION EFFECTS IN THE IONIC CONDUCTIVITY OF POTASSIUM CHLORIDE CRYSTALS [J].

ALLNATT, AR ;

JACOBS, PWM .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1961, 19 (3-4) :281-290

[3] PRODUCTION OF F-CENTERS BY ULTRAVIOLET-IRRADIATION IN SULFUR-DOPED NACL CRYSTAL [J].

BABA, M ;

IKEDA, T ;

YOSHIDA, S .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1976, 15 (02) :231-235

[4] EFFECT OF HEAT-TREATMENT ON IONIC-CONDUCTION AND OPTICAL-ABSORPTION IN SULFUR-DOPED SODIUM-CHLORIDE [J].

BABA, M ;

IKEDA, T ;

YOSHIDA, S .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1975, 14 (09) :1273-1279

[5] ANION DIFFUSION IN CRYSTALS OF NACL [J].

BARR, LW ;

MORRISON, JA ;

SCHROEDER, PA .

JOURNAL OF APPLIED PHYSICS, 1965, 36 (02) :624-+

[6]

BARR LW, 1970, PHYSICAL CHEM ADV TR, V10

[7] VACANCY PAIRS AND CORRELATION EFFECTS IN KCL AND NACL SINGLE-CRYSTALS [J].

BENIERE, M ;

CHEMLA, M ;

BENIERE, F .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1976, 37 (05) :525-538

[8]

BURTON CH, 1970, J PHYS C, V3, P524

[9]

CATLOW CRA, 1976, J PHYSIQUE, V37, P253

[10]

Chandra S., 1970, Canadian Journal of Physics, V48, P397, DOI 10.1139/p70-055