PERTURBATION ANALYSIS OF CATALYTIC CURRENT AT A ROTATING-DISK ELECTRODE

被引：8

作者：

LIN, YP ^{[1
]}

WU, H ^{[1
]}

SELMAN, JR ^{[1
]}

机构：

[1] IIT, DEPT CHEM ENGN, CHICAGO, IL 60616 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 07期

关键词：

D O I：

10.1021/ie00103a017

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A perturbation method has been developed to analyze the kinetics of a catalytic reaction system where the product of a heterogeneous reaction reacts homogeneously to re-form the reactant. This is used to investigate the kinetics of Fenton's reagent using a platinum rotating disk electrode (RDE). The rate constants of the reaction were found to be 135 M-1s-1in the forward direction and 1.5 M-1s-1in the backward direction. © 1990, American Chemical Society. All rights reserved.

引用

页码：1189 / 1194

页数：6

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